Induced polarization thesis

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MATERIAL SYSTEM ENGINEERING FOR ADVANCED ELECTROCALORIC COOLING TECHNOLOGY

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Thesis list | UBC Geophysical Inversion Facility

Essential aspects of the chiral induced spin selectivity CISS effect and their implications for spin-controlled chemistry and asymmetric electrochemical reactions are described. The generation of oxygen through electrolysis is discussed as an example in which chirality-based spin-filtering and spin selection rules can be used to improve the reaction's efficiency and selectivity. Next the discussion shifts to illustrate how the spin selectivity of chiral molecules CISS properties allows one to use the electron spin as a chiral bias for inducing asymmetric reactions and promoting enantiospecific processes. Two enantioselective electrochemical reactions that have used polarized electron spins as a chiral reagent are described; enantioselective electroreduction to resolve an enantiomer from a racemic mixture and an oxidative electropolymerization to generate a chiral polymer from achiral monomers. A complementary approach that has used spin-polarized, but otherwise achiral, molecular films to enantiospecifically associate with one enantiomer from a racemic mixture is also discussed. Each of these reaction types use magnetized films to generate the spin polarized electrons and the enantiospecificity can be selected by choice of the magnetization direction, North pole versus South pole. Possible paths for future research in this area and its compatibility with existing methods based on chiral electrodes are discussed.
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Jump to main content. Conrad Schlumberger Dobrin probably was first to report the induced polarization phenomenon, which he called "provoked polarization. Instead, the potential difference dropped sharply at first, then gradually decayed to zero after a given interval of time. Certain layers in the ground can become electrically polarized, forming a battery when energized with an electric current. Upon turning off the polarizing current, the ground gradually discharges and returns to equilibrium.
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The occurrences of gold and disseminated sulfides lie as a part of the shearing fault zone that extends from the north to the south of the study area for a length of about 25 km. The gold and disseminated sulfides are located on the alteration shear zone which is composed of quartz—feldspathic highly ferruginated rock gossans occupying the eastern and central parts of the area. Mineralogical analyses that were done on bedrock samples of the oxidized and alteration zones indicated that there are two anomalous spots of gold contents; the first one has values ranging from 5 to 49 g ton -1 and the second anomaly has values ranging from to
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